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含钛高炉渣钛富集工艺及钛资源利用
引用本文:邓勇,甄常亮,李俊国,曾亚南,马涛.含钛高炉渣钛富集工艺及钛资源利用[J].中国冶金,2022,32(8):25-31.
作者姓名:邓勇  甄常亮  李俊国  曾亚南  马涛
作者单位:1.华北理工大学冶金工程研究院, 河北 唐山 063210;
2.华北理工大学冶金与能源学院, 河北 唐山 063210;
3.现代冶金技术教育部重点实验室, 河北 唐山 063210
基金项目:河北省自然科学基金-钢铁联合研究基金资助项目(E2020209069)
摘    要:为实现高炉渣中钛的富集和利用,研究了炉渣钛富集的技术手段,分析了炉渣钛资源利用的可能性。结果表明,炉渣中的钛能够以四氯化钛、钛铁合金、钛白、碳化钛形式富集以及选择性析出富集,其中选择性析出富集是一种绿色环保的富集技术。炉渣中钛资源可被用于建筑材料、玻璃材料、功能材料以及肥料,炉渣提钛工艺流程均较为复杂,容易对环境造成污染,并且成本较高。将部分低钛渣直接用于建筑材料或肥料、高钛渣借助选择性析出技术富集后再利用是未来含钛炉渣综合利用研究的重点方向。

关 键 词:含钛高炉渣  富集工艺  选择性析出  钛资源  综合利用  

Titanium enrichment process of titanium bearing blast furnace slag and utilization of titanium resources
DENG Yong,ZHEN Chang-liang,LI Jun-guo,ZENG Ya-nan,MA Tao.Titanium enrichment process of titanium bearing blast furnace slag and utilization of titanium resources[J].China Metallurgy,2022,32(8):25-31.
Authors:DENG Yong  ZHEN Chang-liang  LI Jun-guo  ZENG Ya-nan  MA Tao
Affiliation:1. Institute for Metallurgical Engineering and Technology, North China University of Science and Technology, Tangshan 063210, Hebei, China; 2. College of Metallurgy and Energy, North China University of Science and Technology, Tangshan 063210, Hebei, China; 3. Ministry of Education Key Laboratory of Modern Metallurgy Technology, Tangshan 063210, Hebei, China
Abstract:In order to realize the enrichment and utilization of titanium in blast furnace slag, the technical means of slag titanium enrichment are studied, and the possibility of slag titanium resource utilization is analyzed. The results show that titanium in slag can be enriched in the form of titanium tetrachloride, ferrotitanium alloy, titanium dioxide, titanium carbide and selective precipitation. Selective precipitation enrichment is a green enrichment technology. Titanium resources in slag can be used as building materials, glass materials, functional materials and fertilizers. The technological processes of slag titanium extraction are complex, easy to pollute the environment and high cost. Some low titanium slag is directly used in building materials or fertilizers, the reuse of high titanium slag after enrichment by selective precipitation technology is the key direction for comprehensive utilization of titanium containing slag in the future.
Keywords:titanium bearing blast furnace slag  enrichment process  selective precipitation  titanium resources  comprehensive utilization  
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