| 用于水性防锈涂料的BA/St/AN功能乳液的合成 |
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| 引用本文： | 黄兴,张宪康,张新宇,陆丽娜. 用于水性防锈涂料的BA/St/AN功能乳液的合成[J]. 材料保护, 2006, 39(7): 31-34 |
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| 作者姓名： | 黄兴 张宪康 张新宇 陆丽娜 |
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| 作者单位： | 上海大学材料科学与工程学院高分子材料系,上海,201800;上海大学材料科学与工程学院高分子材料系,上海,201800;上海大学材料科学与工程学院高分子材料系,上海,201800;上海大学材料科学与工程学院高分子材料系,上海,201800 |
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| 摘 要： | 为了研制无毒环保的水性防锈涂料,采用丙烯酸丁酯、苯乙烯、丙烯腈、甲基丙烯酸以及磷酸酯功能性单体合成了一种功能性乳液,通过对粒径、凝聚率、吸水率、钙离子稳定性、附着力等性能分析,确定了阴离子型乳化剂与非离子型乳化剂按1:1混合配比,用量为单体总量的3%,自制的磷酸酯功能单体用量为单体总量的2%时,乳液及其涂膜有较好的综合性能.用该乳液配制的水性防锈涂料漆膜在3%的盐水中浸泡时间超过720 h.
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| 关 键 词： | 水性防锈涂料 功能性苯丙乳液 磷酸酯功能单体 |
| 文章编号： | 1001-1560（2006）07-0031-04 |
| 收稿时间： | 2006-03-31 |
| 修稿时间： | 2006-03-31 |
Synthesis of a Copolymerized Emulsified Liquid from Butylacrylate and Styrene and Acrylonitrile for Waterborne Antirust Coating |
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| HUANG Xing,ZHANG Xian-kang,ZHANG Xin-yu,LU Li-na. Synthesis of a Copolymerized Emulsified Liquid from Butylacrylate and Styrene and Acrylonitrile for Waterborne Antirust Coating[J]. Journal of Materials Protection, 2006, 39(7): 31-34 |
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| Authors: | HUANG Xing ZHANG Xian-kang ZHANG Xin-yu LU Li-na |
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| Abstract: | An emulsified liquid used for waterborne antirust coating was synthesized via the copolymerization of butylacrylate (BA), styrene (St), methacrylic acid (MAA), acrylonitrile (AN), and phosphate ester as the functional monomers. The effects of the types and amount of the emulsifiers, the mixing ratio of the anionic and non-ionic emulsifiers, and the amount of the phosphate ester functional monomer on the performance of the emulsified liquid and the coating made of the same were investigated. |
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| Keywords: | waterborne antirust paint styrene-acrylate emulsified liquid phosphate ester |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
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