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氧化钙或氢氧化钙与浓碱铝酸钠溶液的反应特性
引用本文:刘桂华,李小斌,彭志宏,张传福,刘祥民.氧化钙或氢氧化钙与浓碱铝酸钠溶液的反应特性[J].中国有色金属学报,2000,10(2):266-269.
作者姓名:刘桂华  李小斌  彭志宏  张传福  刘祥民
作者单位:中南工业大学冶金系!长沙410083(刘桂华,李小斌,彭志宏,张传福),中州铝厂!焦作454174(刘祥民)
基金项目:博士点基金资助课题! ( 96 0 5330 9)
摘    要:研究了氧化钙、氢氧化钙与浓碱铝酸钠溶液的反应特性,在相同条件下,氧化钙的反应活性高于氢氧化钙,这归结于氧化钙在水化放出大量热量的同时,固相颗凿细化,比表面积增大。较多量的氧化钙加入反应体系后,体系主要因固相颗粒团聚容易发生膨胀。玎的扫描电镜分析表明:加入表面活性剂后,表面活必有因吸附“挤占”了新生因相表面吸附的小分子,破坏或削弱了体系的团聚,从而消除和体系的膨胀;同时,表面活性剂的会降低了固液界面

关 键 词:氧化钙  氢氧化钙  铝酸钠溶液  反应活性  氧化铝
修稿时间:1999-01-04

Reaction behavior between calcium oxide or calcium hydroxide and aluminate solution with heavy caustic soda
LIU Gui hua ,LI Xiao bin ,PENG Zhi hong ,ZHANG Chuan fu ,LIU Xiang min.Reaction behavior between calcium oxide or calcium hydroxide and aluminate solution with heavy caustic soda[J].The Chinese Journal of Nonferrous Metals,2000,10(2):266-269.
Authors:LIU Gui hua  LI Xiao bin  PENG Zhi hong  ZHANG Chuan fu  LIU Xiang min
Affiliation:LIU Gui hua 1,LI Xiao bin 1,PENG Zhi hong 1,ZHANG Chuan fu 1,LIU Xiang min 2 1. Department of Non ferrous Metallurgy,Central South University of Technology,Changsha 410083,P.R.China, 2. Zhongzhou Alumina Factory,Jiaozuo 454174,P.R.
Abstract:The reaction between calcium oxide or calcium hydroxide and aluminate solution with heavy caustic soda was studied. The reaction activity of CaO was better than that of Ca(OH) 2 under the same condition, which was attributed to that the grain size became smaller when the CaO being hydrated, besides the reaction gave out lots of energy and formed a series of active substances. When more amount of CaO was added into the aluminate solution, the slurry's swell changed the system into paste. When some surfactants were added into the reaction system, because the surfactant was adsorbed on the interface between solid and liquid, and the extent of grain agglomeration was reduced, the slurry's swell disappeared. The adsorption of surfactant on the grain stabilized the fine grain, led to increasing the specific surface area and promoting the rate of reaction.
Keywords:calcium oxide  calcium hydroxide  aluminate solution  reactivity
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