Characterization of an Au/n-Si photovoltaic structure with an organic thin film |
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Authors: | C Özaydın K Akkılıç S İlhan Ş Rüzgar Ö Güllü H Temel |
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Affiliation: | 1. Department of Physics, Faculty of Science and Art, University of Batman, Batman, Turkey;2. Department of Physics, Faculty of Education, University of Dicle, 21280 Diyarbak?r, Turkey;3. Department of Chemistry, Faculty of Science and Art, University of Siirt, Turkey;4. Department of Chemistry, Faculty of Education, University of Dicle, Diyarbak?r, Turkey |
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Abstract: | We demonstrate that a copper(II) organic complex can control the electrical characteristics of conventional Au/n-Si metal–semiconductor (MS) contacts. We investigated the electronic and photovoltaic properties of a Cu(II) complex/n-Si heterojunction diode. The ideality factor n and barrier height Φb of the diode were 2.22 and 0.736 eV, respectively. An ideality factor greater than unity indicates that the diode exhibits non-ideal current–voltage behavior. This behavior results from the effect of series resistance and the presence of an interfacial layer. The series resistance and barrier height determined using Norde’s method were 6.7 kΩ and 0.77 eV, respectively. The device showed photovoltaic behavior, with a maximum open-circuit voltage of 0.24 V and a short circuit current of 1.7 μA under light of 8 mW/cm2. |
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Keywords: | Devices Schottky barrier Organics Surfaces and interfaces |
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