| N-甲基-2-(3-硝基苯基)吡咯烷［3′,4′：1,2］［60］富勒烯的合成与性能研究 |
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| 引用本文： | 金波,彭汝芳,舒远杰,黄毅民,王蓉,楚士晋.N-甲基-2-(3-硝基苯基)吡咯烷［3′,4′：1,2］［60］富勒烯的合成与性能研究[J].含能材料,2007,15(3):196-197. |
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| 作者姓名： | 金波 彭汝芳 舒远杰 黄毅民 王蓉 楚士晋 |
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| 作者单位： | 1. 西南科技大学材料科学与工程学院,四川,绵阳,621010
2. 中国工程物理研究院化工材料研究所,四川,绵阳,621900 |
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| 基金项目： | 国家自然科学基金资助项目(10576026)，四川省科技厅重点公关项目纳米专项(03GG009-025,05GG009-018-05)，中国工程物理研究院化工材料研究所协作项目(212032085) |
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| 摘 要： | 以N-甲基甘氨酸、间-硝基苯甲醛和C60为原料反应合成得到了N-甲基-2-(3-硝基苯基)吡咯烷3′,4′:1,2]60]富勒烯(MNPF),产率为95%(以消耗C60计),经紫外光谱、红外光谱、质谱和核磁共振表征了MNPF结构;利用差热分析仪对MNPF的热稳定性进行了研究,初步探讨了MNPF对HMX的钝感作用;结果表明,产物具有良好热稳定性,对HMX有明显钝感作用,添加1%的MNPF可以使HMX的摩擦感度降低到48%,撞击感度降低到50%。
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| 关 键 词： | 有机化学 N-甲基-2-(3-硝基苯基)吡咯烷[3′ 4′:1 2][60]富勒烯(MNPF) 钝感作用 热稳定性 |
| 文章编号： | 1006-9941（2007）03-0196-02 |
| 收稿时间： | 2006/8/28 0:00:00 |
| 修稿时间： | 2006-08-282006-10-30 |
Study on the Synthesis and Properties of N-Methyl-2-(3-nitrophenyl) Fullerenopyrrolidine |
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| JIN Bo,PENG Ru-fang,SHU Yuan-jie,HUANG Yi-ming,WANG Rong and CHU Shi-jin.Study on the Synthesis and Properties of N-Methyl-2-(3-nitrophenyl) Fullerenopyrrolidine[J].Chinese Journal of Energetic Materials,2007,15(3):196-197. |
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| Authors: | JIN Bo PENG Ru-fang SHU Yuan-jie HUANG Yi-ming WANG Rong and CHU Shi-jin |
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| Affiliation: | 1. Southwest University of Science and Technology, Mianyang 621010, China; 2. Institute of Chemical Materials, CAEP , Mianyang 621900, China |
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| Abstract: | N-methyl-2-(3-nitrophenyl)fullerenopyrrolidine (MNPF) was synthesized with sarcosine, m-nitrobenzaldehyde and 60] fullerene as primary substances,the yield of MNPF was 95%(based on consumed C60). Its structure was characterized by UV-vis, IR, MS and NMR. The thermal stability of MNPF was studied by differential thermal analysis (DTA), and the effects of MNPF on the mechanical sensitivity and friction sensitivity of HMX were investigated. The results show that MNPF has good thermal stability. Compared with that of pure HMX, the friction sensitivity and impact sensitivity of HMX with 1% MNPF can be decreased to 48% and 50%, respectively. |
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| Keywords: | organic chemistry N-methyl-2-(3-nitrophenyl)fullerenopyrrolidine (MNPF) insensitive action thermal stability |
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