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Low-temperature synthesis of CdCu3Ti4O12 powders with high dielectric permittivities
Authors:Zhanhui Peng  Pengfei Liang  Bi Chen  Yichen Xiang  Hui Peng  Di Wu  Xiaolian Chao  Zupei Yang
Affiliation:1. Key Laboratory for Macromolecular Science of Shaanxi Province, Shaanxi Key Laboratory for Advanced Energy Devices, Shaanxi Engineering Laboratory for Advanced Energy Technology, School of Materials Science and Engineering, Shaanxi Normal University, Xi''an, 710062, Shaanxi, China;2. School of Physics and Information Technology, Shaanxi Normal University, Xi''an, 710062, Shaanxi, China
Abstract:The molten salt method was adopted in this work to synthesize CdCu3Ti4O12 precursor powders and was found capable of notably reducing the sintering temperature. It was also found that the grain size gradually increases and the grain shape changes from spherical to cubic with increasing proportions of molten salt. The optimal sintering conditions were found to be at approximately 730?°C with the addition of 20% molten salt. After further sintering at 975?°C, the obtained perovskite ceramics exhibited a high dielectric constant at low frequencies.
Keywords:Molten salt method  Low-energy sintering  Perovskite phase  High dielectric constant
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