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铸造单晶硅性能和应用分析
引用本文:明亮,黄美玲,段金刚,王锋,黄少文,周浪. 铸造单晶硅性能和应用分析[J]. 太阳能学报, 2022, 43(1): 335-340
作者姓名:明亮  黄美玲  段金刚  王锋  黄少文  周浪
作者单位:南昌大学光伏研究院;湖南红太阳光电科技有限公司;山西中电科新能源技术有限公司
基金项目:水电硅材料产业发展关键技术研究及应用(20192E007)。
摘    要:以G6型多晶硅定向凝固铸锭炉生长的铸造单晶硅为研究对象,对其性能特点及应用进行分析.铸造单晶硅中含有位错、亚晶粒、多晶晶粒、间隙态元素和硬质点等缺陷.在铸造单晶硅制备过程中,因长晶界面不平及杂质存在的原因,硅锭生长时存在较大的应力,致使硅原子排列出现错排,从而导致位错、亚晶粒和多晶晶粒的产生,其中多晶晶粒的晶向主要有(...

关 键 词:晶体生长  位错  电池效率  铸造单晶硅  性能

PROPERTIES AND APPLICATION ANALYSIS OF CASTING MONOCRYSTALLINE SILICON
Ming Liang,Huang Meiling,Duan Jin'gang,Wang Feng,Huang Shaowen,Zhou Lang. PROPERTIES AND APPLICATION ANALYSIS OF CASTING MONOCRYSTALLINE SILICON[J]. Acta Energiae Solaris Sinica, 2022, 43(1): 335-340
Authors:Ming Liang  Huang Meiling  Duan Jin'gang  Wang Feng  Huang Shaowen  Zhou Lang
Affiliation:(Institute of Photovoltaics,Nanchang University^Nanchang 330031,China;Hunan Red Solar Photoelectricity Science and Technology Co.,Ltd.,Changsha 410205,China;Shanxi Zhongdianke New Energy Technology Co.,Ltd.,Taiyuan 030032,China)
Abstract:The performance characteristics and application of casting monocrystalline silicon produced by G6 type polysilicon directional solidification furnace were analyzed.The results show that the casting monocrystalline silicon contains dislocations,subgrains,polycrystalline grains,interstitial elements and hard points.During the production process of casting monocrystalline silicon,the dislocation,sub-grains and polycrystalline grains were generated by the misalignment of the silicon atoms which caused by the large stress from the uneven crystal growth interface and impurities,the main orientation of these polycrystalline grains was(331)etc,and the dislocation was easy to form in the middle and upper part of silicon ingots and proliferate with the crystal growth of the crystal.The distribution of interstitial elements Fe and O in casting monocrystalline silicon was similar to that of cast polysilicon.The main components of the hard points were silicon nitride and silicon carbide.At last,the conversion efficiency of PERC cell produced by casting monocrystalline silicon wafer with low defect density was 21.7%,0.4%lower than that of the czochralski silicon which under the same cell process.
Keywords:grain growth  dislocation  cell efficiency  casting monocrystalline silicon  performance
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