Abstract: | Acyloxy derivatives of silicon were prepared by the interchange reaction between carboxylic acids (including various grades of palmitic acid) and tetraethoxysilane, and by the interchange reaction between palmitic acid and technical ethyl silicate (silica content 40%) or technical isopropyl silicate (silica content 38%). In most of the reactions, sodium methoxide was used as catalyst. Some physical properties of the reaction products were determined, and the materials made from palmitic acid were evaluated as water-repellent coatings on cotton cloth. |