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Mechanically activated aluminothermic reduction of titanium dioxide
Authors:A. R. Kamali  J. Fahim
Affiliation:(1) Materials Science Department, Malek-e-Ashtar University of Technology, Isfahan, Iran
Abstract:Addressed is the effect of ball milling on aluminothermic reduction of TiO2. In 0.5-h milled 3TiO2 + Al mixtures, a two-step reaction was found to yield TiAl and Ti3Al. Upon an increase in the milling time (to 20 h), a one-step reaction yielded TiAl. The activation energy for TiAl formation was 75 kJ mol−1 for 0.5-h milled samples and 33 kJ mol−1 for 20-h milled samples. The article is published in the original.
Keywords:aluminothermic reduction  ball milling  activation energy  titanium aluminides
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