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Single and coupled electrochemical bursters during the electrodissolution/passivation of iron
Authors:A. Karantonis  D. Koutsaftis  N. Kouloumbi
Affiliation:Department of Materials Science and Engineering, School of Chemical Engineering, National Technical University of Athens, 15780 Zografou, Athens, Greece
Abstract:The ability to produce bursting electrochemical oscillations via the slow external variation of the applied potential is investigated during the electrodissolution/passivation of iron in sulfuric acid. The results are compared with those concerning spontaneous electrochemical bursting in the presence of chloride ions. Moreover, an assembly of two electrochemical Fe/H2SO4bursters is studied experimentally. The effect of phase space topology on synchrony is explored by studying the coupled response for different types of electrochemical bursters.
Keywords:Iron electrodissolution   Passivation   Oscillations   Bifurcations   Bursting
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