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Preparation of La(OH)3 and La2O3 with Rod Morphology by Simple Hydration of La2O3
引用本文:丁家文 吴燕利 孙伟丽 李永绣. Preparation of La(OH)3 and La2O3 with Rod Morphology by Simple Hydration of La2O3[J]. 中国稀土学报(英文版), 2006, 24(4): 440-442. DOI: 10.1016/S1002-0721(06)60139-7
作者姓名:丁家文 吴燕利 孙伟丽 李永绣
作者单位:Research Center for Rare Earths & Micro/Nano Functional Materials, Nanchang University, Nanchang 330047, China
基金项目:国家自然科学基金,江西省自然科学基金,江西省教育厅资助项目
摘    要:Lanthanum hydroxide with rod-like morphology was synthesized with simple hydration processing via the hydration of its bulk oxide in normal water solution at boiling temperature. An XRD pattern shows the formation of the hexagonal phase of La(OH)3, indicating that the hydration process is very rapid. The as-prepared La(OH)3 is almost entirely with a needle- or rod-like shape with a width of 2 - 3 μm and a length of 5 - 8 μm. The mechanism of the formation of La(OH)3 with rod-like morphology was preliminarily presented. It is easier to expand the simple hydration process on a large scale than the hydrothermal process.

关 键 词:氢氧化镧 水合作用 稀土 性能
文章编号:1002-0721(2006)04-0440-03
收稿时间:2005-09-18
修稿时间:2005-11-16

Preparation of La(OH)3 and La2O3 with Rod Morphology by Simple Hydration of La2O3
Jiawen , Yanli Wu, Weili Sun,Yongxiu Li,. Preparation of La(OH)3 and La2O3 with Rod Morphology by Simple Hydration of La2O3[J]. Journal of Rare Earths, 2006, 24(4): 440-442. DOI: 10.1016/S1002-0721(06)60139-7
Authors:Jiawen    Yanli Wu   Weili Sun  Yongxiu Li  
Affiliation:aResearch Center for Rare Earths & Micro/Nano Functional Materials, Nanchang University, Nanchang 330047, China
Abstract:Lanthanum hydroxide with rod-like morphology was synthesized with simple hydration processing via the hydration of its bulk oxide in normal water solution at boiling temperature. An XRD pattern shows the formation of the hexagonal phase of La(OH)3, indicating that the hydration process is very rapid. The as-prepared La(OH)3 is almost entirely with a needle- or rod-like shape with a width of 2~3 μm and a length of 5~8 μm. The mechanism of the formation of La(OH)3 with rod-like morphology was preliminarily presented. It is easier to expand the simple hydration process on a large scale than the hydrothermal process.
Keywords:rod morphology  lanthanum hydroxide  hydration  rare earths
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