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界面张力弛豫方法研究复合驱油水界面膜的扩张性质
引用本文:方洪波,罗澜,张路,王宜阳,赵濉,俞稼镛.界面张力弛豫方法研究复合驱油水界面膜的扩张性质[J].石油勘探与开发,2004,31(Z1):26-29.
作者姓名:方洪波  罗澜  张路  王宜阳  赵濉  俞稼镛
作者单位:1. 中国石化胜利油田勘探设计研究院
2. 中国科学院理化技术研究所
基金项目:国家基础研究发展规划(973)项目(G19990225)
摘    要:界面张力弛豫方法是研究油水界面膜微观性质极为有效的方法.采用该方法研究了驱油体系中化学剂如聚合物、十二烷基苯磺酸钠、碱对原油活性组分界面膜扩张黏弹性质的影响,考察了界面上的微观弛豫过程.研究发现,驱油体系中化学剂均对原油活性组分界面膜的性质有一定的影响,尤其是聚合物和碱的加入使界面上出现了特征时间在103s数量级的慢弛豫过程,大大增强了界面膜的弹性.表面活性剂与活性组分间的相互作用造成扩张黏性部分明显变化,而弹性变化不大.图6表1参5

关 键 词:扩张模量  相角  界面张力弛豫  驱油体系
文章编号:1000-0747(2004)增刊-0026-04
修稿时间:2004年8月23日

Dilational properties of interfacial film in FOR by interfacial tension relaxation method
FANG Hong-bo,LUO Lan,ZHANG Lu,WANG Yi-yang,ZHAO Sui,YU Jia-yong.Dilational properties of interfacial film in FOR by interfacial tension relaxation method[J].Petroleum Exploration and Development,2004,31(Z1):26-29.
Authors:FANG Hong-bo  LUO Lan  ZHANG Lu  WANG Yi-yang  ZHAO Sui  YU Jia-yong
Affiliation:Prospecting and Design-ing Research Institute, Shengli Petroleum Administrative Bureau,Shandong 257062,China;Technical Institute of Physics and Chemistry, CAS, Beijing 100101, China;Technical Institute of Physics and Chemistry, CAS, Beijing 100101, China;Technical Institute of Physics and Chemistry, CAS, Beijing 100101, China;Technical Institute of Physics and Chemistry, CAS, Beijing 100101, China;Technical Institute of Physics and Chemistry, CAS, Beijing 100101, China
Abstract:The effects of chemicals in FOR system, such as polymer,sodium lauryl benzene sulfonate and alkali, on interfacial dilational viscoelasticity behaviors of decane-water interfaces were investigated by the method of interfacial tension relaxation. It showed that the slow relaxation processes with characteristic time of l03s orders ap-peared with the addition of polymer or alkali. The elasticity of film increased with the appearance of slow relaxation processes.
Keywords:dilational modulus  phase angle  interfacial tension relaxation  FOR system
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