| BC-114型苯氧化催化剂的活性校正 |
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| 引用本文： | 高广达,徐以撒.BC-114型苯氧化催化剂的活性校正[J].石油化工,1985(6). |
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| 作者姓名： | 高广达 徐以撒 |
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| 作者单位： | 江苏化工学院 常州 |
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| 摘 要： | 根据常州曙光化工厂苯氧化固定床反应器的实测数据,用Alussuise型V-Mo系催化剂的宏观动力学方程,与国产同类型BC-114催化剂相比较,用活性校正系数a修正动力学方程,并由二元多项式回归法得a值与苯转化率x_B、反应温度T间的关联式为: a=0.6234+3.3974x_B+6.8238×10~(-3)T-1.5164×10~(-3)x_BT-3.1569x_B~2-9.5492×10~(-5)T~2
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A corrective factor for the activity of BC-114 catalyst for benzene oxidation |
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| Abstract: | Chemical plant operating data of BC-114 catalyst in fixed bed reactor for benzene oxidation werecompared with kinetic equations of Alussuise type V-Mo catalyst. A factor was proposed to correct for the catalytic activity of BC-114. An equation correlating a with the reaction temperature and the conversion rate was presented. |
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