Steel Desulphurisation and Sulphur Bonding in Solidified Ladle Slags

It was investigated in which form sulphur is bonded in ladle slags. For this purpose, the mineralogical phases of the ladle slags were qualitatively and quantitatively evaluated by means of a microprobe. This slag characterisation allowed reconstructing the bonding of sulphur into the phases of the ladle slag. Moreover, the reaction process with regard to the ionic theory as well as the structural formula for the mechanism of sulphur bonding were discussed. The bonding of sulphur into calcium aluminate slags is determined by the sulphide ion content in the slag as well as by the ratio of (CaO)/(Al₂O₃). Calcium sulphide separates only if the slag contains a large number of sulphide ions. When Ca₁₂Al₁₄O₃₃ is separated the sulphide ion is successively integrated into the lattice. The crystal lattice of Ca₁₂Al₁₄O₃₃ is characterised by an open, three‐dimensional anionic network composed of aluminium‐oxygen tetrahedrons linking the edges. In this network, large interstitial spaces are formed, which may be filled with calcium ions on the one hand and statistically with a free oxygen or sulphide ion on the other hand.