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Thermally-exfoliated graphene Oxide/ZnO nanocomposite catalysts for photocatalytic hydrogen evolution and antibacterial activities
Affiliation:1. Selcuk University, Department of Biotechnology, 42030, Konya, Türkiye;2. Selcuk University, Department of Biochemistry, 42030, Konya, Türkiye;3. Karamanoglu Mehmetbey University, Department of Metallurgy and Materials Engineering, 70200, Karaman, Türkiye;4. Suleyman Demirel University, Department of Mechanical Engineering, 32260, Isparta, Türkiye;5. Sabanci University Integrated Manufacturing Technologies Research and Application Center & Composite Technologies Center of Excellence, Teknopark Istanbul, Pendik, 34906, Istanbul, Türkiye;6. Faculty of Engineering and Natural Sciences, Materials Science and Nanoengineering, Sabanci University, Tuzla, 34956, Istanbul, Türkiye;7. Advanced Membrane Technology Research Centre (AMTEC), Faculty of Chemical and Energy Engineering, Universiti Teknologi Malaysia, 81310 UTM Johor Bahru, Johor, Malaysia;8. Selcuk University, Department of Chemistry, 42030, Konya, Türkiye;1. U.S. Department of Energy, National Energy Technology Laboratory, 3610 Collins Ferry Road, P.O. Box 880, Morgantown, WV, 26507-0880;2. NETL Support Contractor, 3610 Collins Ferry Road Morgantown, WV, 25607, USA;1. Department of Mechanical, Mechatronics and Manufacturing Engineering, University of Engineering and Technology Lahore, Faisalabad, Pakistan;2. Department of Mechatronics and Control Engineering, University of Engineering and Technology Lahore, Pakistan;3. U.S. Pakistan Centre for Advanced Studies in Energy, National University of Sciences and Technology, Islamabad, Pakistan;4. School of Industrial Engineering, Pontificia Universidad Católica de Valparaíso, Valparaíso, Chile;5. Stokes Laboratories and Bernal Institute, School of Engineering, University of Limerick, Limerick, Ireland;1. Nikolaev Institute of Inorganic Chemistry SB RAS, Ac. Lavrentiev ave., 3, Novosibirsk, 630090, Russian Federation;2. Department of Petroleum Engineering, Kazan Federal University, Kremlevskaya str. 18, Kazan, 420008, Russian Federation;1. Dipartimento di Ingegneria Industriale-DIIN, Università Degli Studi di Salerno and CNR-SPIN, 84084 Fisciano SA, Italy;2. Dipartimento di Ingegneria Industriale-DIIN, Università Degli Studi di Salerno, 84084 Fisciano SA, Italy;3. Dipartimento di Fisica “E.R. Caianiello”, Università Degli Studi di Salerno, and CNR-SPIN, 84084 Fisciano SA, Italy;4. SOLIDpower S.p.A, 38017 Mezzolombardo TN, Italy;1. Department of Electrical Automation, Hebei University of Water Resources and Electric Engineering, Cangzhou, 061001, China;2. Computer Department, Hebei University of Water Resources and Electric Engineering, Cangzhou, 061001, China;3. Enrolment and Vocation Guidance Office, Hebei University of Water Resources and Electric Engineering, Cangzhou, 061001, China;4. Electrical Engineering Department, Sun-Life Company, Baku, Azerbaijan
Abstract:Carbon nanomaterials are of great interest due to their enhanced charge separation in hydrogen evolution reactions. Herein, heterostructured TEGO/ZnO nanocomposite catalyst was obtained by combining 3D multilayer graphene-like nanomaterial obtained by green process from recycled carbon source with ZnO to improve photocatalytic activity. Here, photodeposition of MoSx and Pt in aqueous solution is performed on TEGO/ZnO nanocomposite to obtain TEGO/ZnO/MoSx and TEGO/ZnO/Pt by reducing (NH4)2MoS4 and H2PtCl6.6H2O, respectively. Photodeposited MoSx and Pt on TEGO/ZnO nanocomposite resulted in enhanced photocatalytic activity and stability due to increased active sites and enhanced electron transfer ability due to cocatalyst effect. In addition, antibacterial activity of TEGO/ZnO nanocomposite against Escherichia coli and Staphylococcus aureus was investigated by bacterial growth kinetic assay. This work could open up a new nanomaterial for chemical and biological applications.
Keywords:Antibacterial activity  Carbon nanomaterials  Graphene-derived materials  Hydrogen evolution  Nanocomposite catalyst
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