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Synthesis and sensitivity properties of Pd-doped tin oxide nanoparticles dispersed in mesoporous silica
Affiliation:1. School of Chemical Engineering, Hefei University of Technology, Tunxi Road 193 Hefei, Anhui 230009, China;2. Institute of Solid State Physics, Chinese Academy of Sciences, Hefei, Anhui 230031, China;1. Shandong Provincial Key Laboratory of Detection Technology for Tumor Markers, School of Chemistry and Chemical Engineering, School of Life Science, Linyi University, Linyi 276005, PR China;2. Collaborative Innovation Center of Functionalized Probes for Chemical Imaging in Universities of Shandong, Shandong Normal University, Jinan 250014, PR China;1. Shandong Provincial Key Laboratory of Detection Technology for Tumor Markers, School of Chemistry and Chemical Engineering, School of Life Science, Linyi University, Linyi 276005, PR China;2. Collaborative Innovation Center of Functionalized Probes for Chemical Imaging in Universities of Shandong, Shandong Normal University, Jinan 250014, PR China;2. Russian Research Oncology Center n.a. N.N. Blokhin of the Russian Academy of Medical Sciences, Moscow, Russia;3. Országos Korányi TBC és Pulmonológiai Intézet, Budapest, Hungary;4. Department of Pulmonology, Markusovszky University Hospital, Budapest, Hungary;6. Arkhangelsk Regional Clinical Oncology Dispensary, Perm, Russia;5. Department of Internal Medicine, National Taiwan University Hospital, Taipei City, Taiwan;11. Department of Thoracic Oncology, Lung Clinic Grosshansdorf, Member of the German Center for Lung Research (DZL), Grosshansdorf, Germany
Abstract:Pd-doped tin oxide nanoparticles dispersed in mesoporous silica were prepared by a thermal-decomposing method and characterized by isothermal nitrogen adsorption measurement, X-ray diffraction (XRD) and transmission electron microscopy (TEM). Tin oxide nanoparticles grow up slowly owing to confinement of the pores of the mesoporous silica. Due to the unique microstructure of the mesoporous silica, the obtained nanocomposite consists of a three-dimensional web of interconnected crystallites of tin oxide and exhibits electronic conductivity when enough tin oxide is assembled in the silica pores. The obtained nanocomposite has also a large specific surface area, and the tin oxide nanoparticles have a free surface in contact with the ambient air. Therefore, the samples exhibit a high sensitivity to CO gas, and have potential application.
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