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Fabrication and mechanical/conductive properties of multi-walled carbon nanotube (MWNT) reinforced carbon matrix composites
Affiliation:1. Key Laboratory of Carbon Materials, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China;2. Graduate School of the Chinese Academy of Sciences, Beijing 100039, China;1. Key Laboratory for Thermal Science and Power Engineering of Ministry of Education, Department of Engineering Mechanics, Tsinghua University, Beijing 100084, China;2. Yushan Administrative Center, Yushan District, Maanshan 243000, China;1. Institute of Engineering Thermophysics, Chinese Academy of Sciences, Beijing, 100190, China;2. University of Chinese Academy of Sciences, Beijing, 100049, China;1. School of Physics and Optoelectronic Technology, Dalian University of Technology, Dalian 116024, PR China;2. Department of Mechanical Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871, Japan
Abstract:Multi-walled carbon nanotube (MWNT) reinforced carbon matrix (MWNT/C) composites have been explored using mesophase pitch as carbon matrix precursor in the present work. Results show that carbon nanotubes (CNTs)can enhance the mechanical properties of carbon matrix significantly. The maximal increment of the bending strength and stiffness of the composites, compared with the carbon matrix, are 147% and 400%, respectively. Whereas the highest in-plane thermal conductivity of the composites is 86 W m? 1 K? 1 which much lower than that of carbon matrix (253 W m? 1 K? 1).At the same time the electrical resistivity of the composites is much higher than that of matrix. It is implicated that CNTs seem to play the role of thermal/electrical barrier in the composites. FSEM micrograph of the fracture surface for the composites shows that the presence of CNTs restrains the crystallite growth of carbon matrix, which is one of factors that improve mechanical properties and decrease the conductive properties of the composites. The defects and curved shape of CNTs are also the affecting factors on the conductive properties of the composites.
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