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Current situation and development prospects of metallurgical by-product gas utilization in China's steel industry
Affiliation:1. State Key Laboratory of Advanced Metallurgy University of Science and Technology Beijing, Beijing, 100083, PR China;2. Chongqing Materials Research Institute Co., LTD, Chongqing, 400700, PR China;1. Department of Materials Science and Engineering, National Yang Ming Chiao Tung University, Hsinchu, 300, Taiwan;2. Department of Materials Science and Engineering, Feng Chia University, Taichung, 407, Taiwan;1. Khristianovich Institute of Theoretical and Applied Mechanics of SB RAS, 630090, Novosibirsk-90, Institutskaya Str. 4/1, Russian Federation;2. Voevodsky Institute of Chemical Kinetics and Combustion of SB RAS, 630090, Novosibirsk-90, Institutskaya Str. 3, Russian Federation;3. Novosibirsk State University, Novosibirsk-90, Pirogov Str. 2, 630090, Russian Federation;1. Department of Chemical Engineering, Graduate School of Engineering, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka-shi, Fukuoka, 819-0395, Japan;2. Department of Materials and Life Science, Faculty of Science and Technology, Seikei University, 3-3-1 Kichijoji-kitamachi, Musashino-shi, Tokyo, 180-8633, Japan;3. Research Center for Synchrotron Light Applications, Kyushu University, 6-1 Kasuga-koen, Kasuga-shi, Fukuoka, 816-8580, Japan;1. Department of Chemical Engineering Materials Environment, SAPIENZA University of Rome, Via Eudossiana 18, 00184, Rome, Italy;2. Key Laboratory of Agro-Forestry Environmental Processes and Ecological Regulation of Hainan Province-College of Ecology & Environment, Hainan University, 570228, Haikou, China
Abstract:China's annual metallurgical by-product gas production exceeds 1400 billion Nm3, the calorific equivalent of ∼266 million tonnes of coal. The widely-studied blast furnace gas used in hydrogen-enriched carbonic oxide recycling oxygenate furnaces ensures carbon-reduction. Converter gas contains abundant heat resources, equivalent to ∼6.5 million tonnes of coal. Using high-temperature by-product gas online reforming methods to convert thermal energy into chemical energy and combining it with power generation and other industries imparts physical heat recovery exceeding 60%. China's annual coke oven gas (COG) production could support more than 100 million tonnes of direct reduced iron production, thus reducing CO2 emissions by more than 150 million tonnes (nearly 10% of China's steel industry CO2 emissions). We summarise the characteristics, availability, and steel-chemical co-production utilisation of three by-product gases, and discuss the application of COG in direct reduced iron production and development of metallurgical by-product gas utilisation for carbon reduction in China.
Keywords:Metallurgical by-product gas  Steel-chemical co-production  Direct reduced iron production  Hydrogen metallurgy  Carbon emission reduction  BF"  },{"  #name"  :"  keyword"  ,"  $"  :{"  id"  :"  kwrd0040"  },"  $$"  :[{"  #name"  :"  text"  ,"  _"  :"  blast furnace  BF-BOF"  },{"  #name"  :"  keyword"  ,"  $"  :{"  id"  :"  kwrd0050"  },"  $$"  :[{"  #name"  :"  text"  ,"  _"  :"  blast furnace-basic oxygen furnace  BFG"  },{"  #name"  :"  keyword"  ,"  $"  :{"  id"  :"  kwrd0060"  },"  $$"  :[{"  #name"  :"  text"  ,"  _"  :"  blast furnace gas  CCPP"  },{"  #name"  :"  keyword"  ,"  $"  :{"  id"  :"  kwrd0070"  },"  $$"  :[{"  #name"  :"  text"  ,"  _"  :"  gas–steam combined cycle power plants  CCS"  },{"  #name"  :"  keyword"  ,"  $"  :{"  id"  :"  kwrd0080"  },"  $$"  :[{"  #name"  :"  text"  ,"  _"  :"  carbon capture and storage  CCU"  },{"  #name"  :"  keyword"  ,"  $"  :{"  id"  :"  kwrd0090"  },"  $$"  :[{"  #name"  :"  text"  ,"  _"  :"  carbon capture and utilisation  COG"  },{"  #name"  :"  keyword"  ,"  $"  :{"  id"  :"  kwrd0100"  },"  $$"  :[{"  #name"  :"  text"  ,"  _"  :"  coke oven gas  DRI"  },{"  #name"  :"  keyword"  ,"  $"  :{"  id"  :"  kwrd0110"  },"  $$"  :[{"  #name"  :"  text"  ,"  _"  :"  direct reduced iron  DRM"  },{"  #name"  :"  keyword"  ,"  $"  :{"  id"  :"  kwrd0120"  },"  $$"  :[{"  #name"  :"  text"  ,"  $$"  :[{"  #name"  :"  __text__"  ,"  _"  :"  CH"  },{"  #name"  :"  inf"  ,"  $"  :{"  loc"  :"  post"  },"  _"  :"  4"  },{"  #name"  :"  __text__"  ,"  _"  :"   dry reforming  HyCROF"  },{"  #name"  :"  keyword"  ,"  $"  :{"  id"  :"  kwrd0130"  },"  $$"  :[{"  #name"  :"  text"  ,"  _"  :"  hydrogen-enriched carbonic oxide recycling oxygenate furnace  LCA"  },{"  #name"  :"  keyword"  ,"  $"  :{"  id"  :"  kwrd0140"  },"  $$"  :[{"  #name"  :"  text"  ,"  _"  :"  Life Cycle Assessment  LDG"  },{"  #name"  :"  keyword"  ,"  $"  :{"  id"  :"  kwrd0150"  },"  $$"  :[{"  #name"  :"  text"  ,"  _"  :"  converter gas  NG"  },{"  #name"  :"  keyword"  ,"  $"  :{"  id"  :"  kwrd0160"  },"  $$"  :[{"  #name"  :"  text"  ,"  _"  :"  natural gas  PSA"  },{"  #name"  :"  keyword"  ,"  $"  :{"  id"  :"  kwrd0170"  },"  $$"  :[{"  #name"  :"  text"  ,"  _"  :"  pressure swing adsorption  STG"  },{"  #name"  :"  keyword"  ,"  $"  :{"  id"  :"  kwrd0180"  },"  $$"  :[{"  #name"  :"  text"  ,"  _"  :"  steam turbine generator  TRT"  },{"  #name"  :"  keyword"  ,"  $"  :{"  id"  :"  kwrd0190"  },"  $$"  :[{"  #name"  :"  text"  ,"  _"  :"  Blast Furnace Top Gas Recovery Turbine Unit  TSA"  },{"  #name"  :"  keyword"  ,"  $"  :{"  id"  :"  kwrd0200"  },"  $$"  :[{"  #name"  :"  text"  ,"  _"  :"  temperature swing adsorption  TCE"  },{"  #name"  :"  keyword"  ,"  $"  :{"  id"  :"  kwrd0210"  },"  $$"  :[{"  #name"  :"  text"  ,"  _"  :"  tonne of standard coal equivalent  TCS"  },{"  #name"  :"  keyword"  ,"  $"  :{"  id"  :"  kwrd0220"  },"  $$"  :[{"  #name"  :"  text"  ,"  _"  :"  tonne of crude steel  VSA"  },{"  #name"  :"  keyword"  ,"  $"  :{"  id"  :"  kwrd0230"  },"  $$"  :[{"  #name"  :"  text"  ,"  _"  :"  vacuum swing adsorption
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