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磷酸根离子缓释体系在电解液中的应用
引用本文:廖振华,陈建军,罗旭芳,徐永进. 磷酸根离子缓释体系在电解液中的应用[J]. 应用化工, 2008, 37(1): 112-113,116
作者姓名:廖振华  陈建军  罗旭芳  徐永进
作者单位:深圳清华大学研究院,广东,深圳,518057
摘    要:磷酸化合物在低压高含水电解液中的抑水合作用往往难以持久。通过合理选用螯合剂、金属核心及磷酸化合物,开发了一种磷酸根离子缓释体系,能够在电解液中慢慢释放出磷酸根离子,可长期适当量地保持电解液中的磷酸根离子,长时间有效抑制水合作用。含有该缓释体系的电解液经产品试制检验,105℃贮存1000 h无异常,且105℃寿命在2000 h以上,性能优良。

关 键 词:磷酸根离子  螯合剂  电解液  缓释  水合
文章编号:1671-3206(2008)01-0112-02
收稿时间:2007-11-09
修稿时间:2007-11-09

Application of phosphate ion controlled-release system in working electrolyte
LIAO Zhen-hua,CHEN Jian-jun,LUO Xu-fang,XU Yong-jin. Application of phosphate ion controlled-release system in working electrolyte[J]. Applied chemical industry, 2008, 37(1): 112-113,116
Authors:LIAO Zhen-hua  CHEN Jian-jun  LUO Xu-fang  XU Yong-jin
Abstract:As the hydration-inhibitor in low voltage working-electrolyte with high water-content,phosphate couldn't work for a long time.So the phosphate ion controlled-release system was developed by selecting chelating agent,metal and phosphate.While the phosphate ion controlled-release system was added into the working electrolyte,the phosphate ion could be released slowly from the system and the amount of phosphate ion in working electrolyte shall be proper in life time.An aluminum electrolytic capacitor comprising such an electrolyte had excellent high-temperature characteristic for 2 000 h under load and 1 000 h under no load,at 105 ℃.
Keywords:phosphate ion    chelating agent    electrolyte solution    controlled-release    hydration
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