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Camphor-based carbon nanotubes as an anode in lithium secondary batteries
Affiliation:1. Chemistry Department, Indian Institute of Technology, Bombay 400076, India;2. School of Chemistry, Physics and Environmental Science, University of Sussex, Brighton, BN1 9Q, UK;3. Department of Applied Chemistry, Faculty of Engineering, Oita University, Dannoharu 700, Oita 870-1192, Japan;1. Department of Chemistry, Nanchang University, Nanchang, 330031, China;2. College of Chemistry and Bio-engineering, Yichun University, Yichun, 336000, China;1. Department of Laboratory Medicine, Guizhou Provincial People''s Hospital, Affiliated Hospital of Guizhou University, Guiyang 550002, Guizhou, China;2. Special Key Laboratory of Oral Diseases Research, Higher Education Institutions of Guizhou Province, Zunyi Medical University, Zunyi 563099, Guizhou, China;3. Department of Cell Biology and Genetics, Zunyi Medical University, Zunyi 563099, Guizhou, China;1. Radioanalytical Chemistry Division, Bhabha Atomic Research Centre, Mumbai 400085, India;2. Fuel Chemistry Division, Bhabha Atomic Research Centre, Mumbai 400085, India
Abstract:Camphor vapour is pyrolysed in the presence of Fe, Ni and Co powder under a dinitrogen atmosphere at different temperatures (750–1050 °C). While Fe and Ni catalyse the formation of carbon nanotubes (CNs), Co facilitates carbon nanobead growth. The CNs, obtained using a Fe catalyst at 950 °C, are utilised as the anode in Li secondary batteries. The capacity of the batteries constructed in this way is as good as those prepared by graphitic carbon formed in the arc process.
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