Cysteamine-CdTe Quantum Dots Electrochemically Synthesized as Fluorescence Probe for Resveratrol |
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Authors: | Natália S M Ramos Denilson V Freitas Gustavo C S de Souza Tailândia M C Belmiro André F Lavorante Erico Teixeira-Neto Marcelo Navarro Maria C B S M Montenegro Ana Paula S Paim |
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Affiliation: | 1.Departamento de Química Fundamental,Universidade Federal de Pernambuco,Recife,Brazil;2.Departamento de Química,Universidade Federal Rural de Pernambuco,Recife,Brazil;3.Brazilian Nanotechnology National Laboratory (LNNano),Brazilian Center for Research in Energy and Materials (CNPEM),Campinas,Brazil;4.LAQV, REQUIMTE, Departamento de Química Aplicada, Faculdade de Farmácia,Universidade do Porto,Porto,Portugal |
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Abstract: | This work proposes a fluorescent probe based on CdTe quantum dots (QDs) for the determination of resveratrol in wine samples. The synthesis of cysteamine (CA) capped CdTe QD was carried out in a one-pot eco-friendly process, resorting to the electrochemical reduction of metallic tellurium powder in a graphite macroelectrode (cavity cell). The reduced species of tellurium (Te2? and Te22?) migrated to an intermediate compartment of the electrochemical cell and in the presence of a cadmium salt and organic stabilizing agent (CA), forming the colloidal dispersion of CdTe in a single step. Under optimum synthesis conditions, the fluorescence intensity of the prepared nanoparticles varied linearly with the resveratrol concentration in the range from 3.25 to 75 μg L?1 (R2?=?0.9984), with a detection limit of 0.97 μg L?1 and RSD of 3.7% (5.0 μg L?1 resveratrol, n?=?10). The method was successfully applied to the resveratrol determination in wines, with recoveries from 97.8 to 112.4%. Student’s t test was applied and no statistically significant difference was observed between the two methods (HPLC and proposed), with a confidence level of 95% (ttabulated?=?2.45 and tcalculated?=?0.38). The resveratrol determination method, by using CdTe-CA QDs as fluorescence probe, was simple, rapid, inexpensive, and sensitive. |
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