Precious‐Metal‐Free Nanocatalysts for Highly Efficient Hydrogen Production from Hydrous Hydrazine |
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Authors: | Jun Wang Yang Li Yu Zhang |
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Affiliation: | 1. University of Chinese Academy of Sciences, Beijing, P. R. China;2. Key Laboratory of Bio‐inspired Smart Interfacial Science and Technology of Ministry of Education, School of Chemistry and Environment, Beihang University Beijing, P. R. China |
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Abstract: | Hydrous hydrazine (H2NNH2·H2O) has generally been considered a promising hydrogen storage carrier because of inherent advantages such as its high hydrogen content and easy recharging as a liquid. Unfortunately, the decomposition of hydrous hydrazine to H2 is terribly sluggish and/or not entirely favored—a competing decomposition to ammonia may be preferred. This has been the case using noble‐metal catalysts and using non‐precious‐metal‐based catalysts, even at elevated temperatures. To overcome this challenge, non‐precious‐metal‐based Cu@Fe5Ni5 core@shell nanocatalysts are prepared using an in situ seeding‐growth approach. Unexpectedly, the catalyst exerts 100% H2 selectivity and excellent activity and stability toward the complete decomposition of hydrous hydrazine, which is due to the synergistic effect of the core@shell structure. These promising results will certainly promote the effective application of hydrous hydrazine as a potential hydrogen storage material. |
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Keywords: | hydrogen storage hydrous hydrazine catalyst nanocatalysts |
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