Some properties of poly(carbonates) and poly(thiocarbonates) from diphenols with methyl groups in the 3-position in the phenyl rings

Glass transition temperatures and the corresponding activation energies of poly(carbonates) and poly(thiocarbonates) with different side-chain substituents obtained from diphenols with methyl groups in the 3-position in the phenyl rings have been determined by differential scanning calorimetry at several scanning speeds. Partial specific volume and specific refractive index increments have also been obtained by densimetry and refractometry measurements in benzene at 25°C. The effect of the different substituents on these properties has been analysed. © 1998 SCI.