Chemical bath deposition of cadmium sulphide on silicon nitride: Influence of surface treatment on film growth |
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Authors: | P O’Brien MA Malik |
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Affiliation: | a School of Chemistry, University of Manchester, Oxford Road, Manchester M13 9PL, UK b School of Computer Science, University of Manchester, Oxford Road, Manchester M13 9PL, UK |
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Abstract: | Nanoparticulate cadmium sulphide was grown by a chemical bath method on PECVD silicon nitride with various surface treatments. It was found that the packing density of the film increased in the order: untreated surface < mercaptopropyl-derivatised surface < ultra-thin (discontinuous) gold- or platinum-treated surface. This behaviour was rationalised by assuming that surface concentrations of Cd2+ or S2− could be increased over the bulk values by producing a surface with ‘soft base’ or ‘soft acid’ chemistry, respectively.Nanoparticle diameters were larger with ultra-thin platinum treatment than with gold. These observations may allow ordered arrays of cadmium sulphide nanoparticles to be prepared by a masking - gold seeding - bath deposition procedure. |
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Keywords: | Cadmium sulphide Surfaces Semiconductors Nanocrystals |
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