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Tuning the optical properties of alloyed CdSexS1 − x nanoparticles by changing the constituent stoichiometry
Authors:Zhenbang Pi  Longyan Wang  Chao Yang
Affiliation:a Department of Chemistry, College of Chemistry and Molecular Science, Wuhan University, Wuhan 430072, PR China
b Faculty of Material Science and Chemistry Engineering, China University of Geosciences, Wuhan 430074, PR China
c Institute of Solid State Physics, Chinese Academy of Sciences, Hefei, Anhui 230031, PR China
Abstract:The spherical particles CdSexS1 − x with 30-80 nm in radius have been successfully prepared by the hydrothermal reaction at 200 °C. The structure characterization which has been carried out using X-ray diffraction (XRD) shows hexagonal crystal structure. Novel properties have been observed via UV-visual absorption spectra and photoluminescence (PL) spectra. The absorption shoulder and the luminescence emission peaks have been tuned by changing the mole ratio of Se in the CdSexS1 − x samples.
Keywords:CdSexS  &minus     x   Hydrothermal synthesis   Nanoparticles
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