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Preparation of new antimony(0)/polyaniline nanocomposites by a one-pot solution phase method |
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| Authors: | Axel Houdayer Denis Billaud Jacques Lambert |
| Affiliation: | a Laboratoire de Chimie du Solide Minéral (UMR 7555), Université Henri Poincaré, Nancy I, BP 239, 54506 Vandoeuvre les Nancy Cedex, France b UMR CNRS-UHP 7565, Université Henri Poincaré, Nancy I, BP 239, 54506 Vandoeuvre les Nancy Cedex, France c Laboratoire de Chimie Physique et Microbiologie pour l'Environnement (UMR 7564), Université Henri Poincaré, Nancy I, 54600 Villers les Nancy, France d Service Commun de Microscopie Electronique à Transmission, Université Henri Poincaré, Nancy I, BP 239, 54506 Vandoeuvre les Nancy Cedex, France |
| Abstract: | The new Sb(0)/PANI nanocomposite was successfully synthesized by a one-pot solution phase method. Sb(0) particles were first prepared by the reduction of SbCl5 or SbCl3 using t-BuONa-activated NaH in THF. A ligand exchange with aniline on t-BuONa-stabilized Sb(0) particles yielded aniline-stabilized particles. The Sb(0)/PANI nanocomposite was finally obtained by polymerizing aniline-stabilized Sb(0) particles by using ammonium persulfate. The morphology and the structure of the nanocomposite was examined by transmission electron microscopy (TEM), selected-area electron diffraction (SAED), X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). Results obtained show that the Sb(0) precursor has a great influence on the size and the crystallinity of Sb(0) nanoparticles dispersed in PANI. |
| Keywords: | Sb(0) particles Polyaniline Synthesis Nanocomposite |
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