OBSH/MMT复合发泡剂制备方法 |
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引用本文: | 尹晓刚,王野,龚维,陈卓. OBSH/MMT复合发泡剂制备方法[J]. 工程塑料应用, 2016, 0(7). DOI: 10.3969/j.issn.1001-3539.2016.07.023 |
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作者姓名: | 尹晓刚 王野 龚维 陈卓 |
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作者单位: | 贵州师范大学化学与材料科学学院,贵州省功能材料化学重点实验室,贵阳 550001 |
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基金项目: | 贵阳市白云区科技计划项目(白科合同[2014]2129),贵州省科学技术基金项目(黔科合J字[2014]2129号),贵州省科技创新人才团队建设项目(黔科合人才团队[2014]4006号) |
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摘 要: | 采用水溶液插层法、胶体化改性法、超临界二氧化碳插层法三种方法将4,4’–氧代双苯磺酰肼(OBSH)插层到钠基蒙脱土(MMT)层间,制备OBSH/MMT复合发泡剂。通过傅立叶变换红外光谱(FTIR)、热失重(TG)、X射线衍射(XRD)、扫描电子显微镜(SEM)等方法对产品进行表征,探究了不同插层方法对复合发泡剂中OBSH插层量、分解温度以及MMT形貌的影响。实验结果表明,三种插层条件下OBSH均能成功插层至MMT中,且制备方法能够影响复合发泡剂的插层效果及MMT形貌。水溶液插层法制备的复合发泡剂中OBSH含量最多,为12.2%,胶体化改性法次之,超临界二氧化碳插层法最少,为10.7%。同时可以得出超临界二氧化碳插层法更有利于改善MMT的团聚结构,使得MMT变得蓬松、无序。
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关 键 词: | 4,4’-氧代双苯磺酰肼 蒙脱土 复合发泡剂 |
Preparation Method of 4,4'-Oxydibenzenesulfonyl Hydrazide/Montmorillonite Composite Foaming Agent |
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Abstract: | Composite foaming agent were prepared by aqueous solution intercalation method,colloidal modification method and supercritical carbon dioxide intercalation method to insert 4,4’–oxydibenzenesulfonyl hydrazide (OBSH) into Na-montmoril-lonite (MMT). The products were characterized by FTIR,TG,X-ray diffraction and SEM. Under all three conditions,OBSH suc-cessful intercalation to MMT and significantly affect the morphology of MMT. OBSH content of aqueous intercalation is 12.2%, followed by colloid modification method,in the case of supercritical carbon dioxide intercalation,the OBSH content is 10.7%. The supercritical carbon dioxide intercalation MMT structure is more conductive to improving the reunion,so MMT become fluffy and more disorderly. |
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Keywords: | 4,4’-oxydibenzenesulfonyl hydrazide montmorillonite composite foaming agent |
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