Sol-gel synthesis and properties of mixed hydrated oxides HxVxW1−xO3·nH2O |
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Authors: | G.S. Zakharova V.L. Volkov |
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Affiliation: | Institute of Solid-State Chemistry, Ural Division, Russian Academy of Sciences, Pervomaiskaya ul. 91, Yekaterinburg 620219, Russia |
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Abstract: | Compounds of the general formula HxVxW1−xO3·nH2O have been prepared from peroxide solutions using the sol-gel process. Of these compounds, three phases are orthorhombic: WO3·1.5H2O (a = 7.68(3) Å, b = 13.81(5) Å, c = 7.39(3) Å), H0.08V0.08W0.92O3·1.2H2O (a = 5.208(3) Å, b = 10.607(9) Å, c = 5.079(3) Å), and H0.17V0.17W0.83O3·1.5H2O (a = 7.60(3) Å, b = 13.86(5) Å, and c = 7.37(3) Å); and two phases (with x = 0.25 and 0.33; n = 1) are amorphous as probed by X-rays. The thermal properties, IR, and X-ray photoelectron spectra of the compounds synthesized have been studied. The scenario of phase relations of the H2O-H-WO3-V2O5 system has been proposed. |
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Keywords: | A. Oxides B. Sol-gel chemistry C. Infrared spectroscopy C. Thermogravimetric analysis (TGA) C. Photoelectron spectroscopy D. Electrical properties |
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