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Electronic characterization of alkali ruthenium hollandites: KRu4O8, RbRu4O8 and Cs0.8Li0.2Ru4O8
Authors:M.L Foo  Wei-Li Lee  G Lawes  N.P Ong
Affiliation:a Frick Laboratory, Department of Chemistry, Princeton University, Washington Road, Princeton, NJ, USA
b Department of Physics, Princeton University, Washington Road, Princeton, NJ, USA
c Lucent Technologies, Bell Laboratories, Murray Hill, NJ, USA
d Los Alamos National Laboratory, Department of Thermal Physics, Los Alamos, NM, USA
Abstract:Transport, specific heat, and magnetic measurements have been performed on three alkali hollandites: KRu4O8, RbRu4O8, and a newly synthesized Cs analog, Cs0.8Li0.2Ru4O8, which was determined to have space group I4/m (#87) and lattice parameters, a = 10.0850(4) and c = 3.12180(20). In contrast to the ruthenium perovskites, which display a wide range of electrical and magnetic behavior, the alkali hollandites are simple paramagnetic metals.
Keywords:A. Oxides   C. X-ray diffraction   D. Electrical properties   D. Magnetic properties   D. Specific heat
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