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低碳烷烃脱氢催化剂流化特性与耐磨性能
引用本文:杜玉朋,孙乐晶,徐腾,房德仁,任万忠. 低碳烷烃脱氢催化剂流化特性与耐磨性能[J]. 化工进展, 2018, 37(2): 587-591. DOI: 10.16085/j.issn.1000-6613.2017-0867
作者姓名:杜玉朋  孙乐晶  徐腾  房德仁  任万忠
作者单位:烟台大学山东省化学工程与过程重点实验室, 山东 烟台 264005
基金项目:博士启动基金(HY17B11)、山东省高等学校科学技术计划及山东省自然科学基金(ZR2017LB022)项目。
摘    要:将相对廉价的低碳烷烃经催化脱氢转变成高附加值的烯烃,并副产大量氢气,是石化资源高效转化与利用的有效途径。本研究针对自主研发的PBD型低碳烷烃脱氢催化剂,分别从催化剂密度、粒径分布及最小流化速度等多个方面进行了流化特性研究。结果表明,PBD型催化剂具有适宜的粒径分布与颗粒密度,属于Geldart A类颗粒,完全适用于循环流化床脱氢装置。此外,PBD型催化剂的磨耗率仅0.27%,是国内同类型催化剂磨耗率的1/8~1/4,可有望大幅度减少工业装置中催化剂的消耗量。

关 键 词:低碳烷烃  脱氢  催化剂  循环流化床  磨损  
收稿时间:2017-05-11

Fluidization performance and abrasive resistance of low-carbon alkane dehydrogenation catalysts
DU Yupeng,SUN Lejing,XU Teng,FANG Deren,REN Wanzhong. Fluidization performance and abrasive resistance of low-carbon alkane dehydrogenation catalysts[J]. Chemical Industry and Engineering Progress, 2018, 37(2): 587-591. DOI: 10.16085/j.issn.1000-6613.2017-0867
Authors:DU Yupeng  SUN Lejing  XU Teng  FANG Deren  REN Wanzhong
Affiliation:Shandong Provincial Key Laboratory of Chemical Engineering and Process, Yantai University, Yantai 264005, Shandong, China
Abstract:Catalytic dehydrogenation of low-carbon alkane to high-value olefin is a high-efficient way of utilizing petrochemical resources. In this study,the fluidization performance of the catalyst PBD was investigated in terms of particle density, size distribution, and minimum fluidization velocity. The findings indicated that the catalyst PBD with appropriate particle size distribution and density belongs to Geldart A particles which can be readily fluidized. Additionally,the abrasion rate of the catalyst PBD was 0.27%, only 1/8 to 1/4 of that of catalyst R and W, which means a dramatic reduction in catalyst consumption in industrial plants.
Keywords:low-carbon alkane  dehydrogenation  catalyst  circulating fluidized bed  attrition  
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