| 异丁烯制备甲基丙烯醛催化剂的研究进展 |
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| 引用本文： | 李强,王蕾,闫瑞一,李增喜,张锁江. 异丁烯制备甲基丙烯醛催化剂的研究进展[J]. 化学工业与工程, 2007, 24(5): 433-438 |
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| 作者姓名： | 李强 王蕾 闫瑞一 李增喜 张锁江 |
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| 作者单位： | 中国科学院研究生院,北京,100049;中国科学院过程工程研究所,北京,100080;中国科学院过程工程研究所,北京,100080 |
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| 摘 要： | 异丁烯选择氧化制备甲基丙烯醛是异丁烯法制备甲基丙烯酸甲酯的关键步骤.本文综述了异丁烯选择氧化生成甲基丙烯醛催化剂,其中包括复合氧化物催化剂和杂多化合物催化剂等的研究现状,讨论了在Mo-Bi催化剂上异丁烯选择氧化生成甲基丙烯醛的反应机理.
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| 关 键 词： | 甲基丙烯醛 异丁烯 选择氧化 复合氧化物 杂多化合物 |
| 文章编号： | 1004-9533（2007）05-0433-06 |
| 收稿时间： | 2006-07-25 |
| 修稿时间： | 2006-07-25 |
Progress of Catalysts for Isobutylene to Methacrolein |
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| LI Qiang,WANG Lei,YAN Rui-yi,LI Zeng-xi,ZHANG Suo-jiang. Progress of Catalysts for Isobutylene to Methacrolein[J]. Chemical Industry and Engineering, 2007, 24(5): 433-438 |
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| Authors: | LI Qiang WANG Lei YAN Rui-yi LI Zeng-xi ZHANG Suo-jiang |
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| Affiliation: | 1 .Graduate University of the Chinese Academy of Sciences, Beijing 100049, China; 2.Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100080, China |
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| Abstract: | Selective oxidation of isobutylene to methacrolein is a key step in the production of methyl methacrylate from isobutylene.The progress of catalysts,which include composite-oxides catalysts and heteropoly compounds catalysts,for selective oxidation of isobutylene to methacrolein were summarized,the mechanism of this reaction on Mo-Bi catalysts was discussed. |
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| Keywords: | methacrolein isobutylene selective oxidation composite-oxides heteropoly compound |
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