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缓蚀剂MA/TEA的合成及其性能研究
引用本文:余兰兰,孙旭蕊,李妍,郑凯.缓蚀剂MA/TEA的合成及其性能研究[J].化工科技,2013(5):13-16,27.
作者姓名:余兰兰  孙旭蕊  李妍  郑凯
作者单位:[1]东北石油大学化学化工学院,黑龙江大庆163318 [2]大庆油田第二采油厂,黑龙江大庆163414
摘    要:作者以马来酸酐(MA)、三乙醇胺(TEA)为原料,过硫酸铵为引发剂,合成二元共聚物MA/TEA缓蚀剂。实验结果表明,最佳合成条件为聚合温度70℃,聚合时间6h,当共聚物添加量6mg/L,硫脲添加量5mg/L时,缓蚀率85.83%,该二元共聚物缓蚀剂对碳钢挂片有较好的缓蚀效果。聚合物缓蚀剂在碳钢挂片表面形成致密的保护膜,使挂片与酸性介质隔离保护挂片。

关 键 词:合成  缓蚀剂  碳钢

Synthesis and properties of corrosion inhibitor MA/TEA
Yu Lanlan^,Sun Xurui^,Li Yan^,Zheng Kai.Synthesis and properties of corrosion inhibitor MA/TEA[J].Science & Technology In Chemical Industry,2013(5):13-16,27.
Authors:Yu Lanlan^  Sun Xurui^  Li Yan^  Zheng Kai
Affiliation:^2 (1. School of Chemistry and Chemical Engineering, Northeast Petroleum University, Daqing 163318, China 2. The No. 2 Petroleum Production of Daqing Oil Field, Daqing 163414, China)
Abstract:In this paper, the copolymer MA/TEA inhibitor was synthesized using maleic anhydride (MA),triethanolamine (TEA) as raw materials, ammonium persulfate as initiator. The experimental results showed that,when the polymerization temperature of the copolymer MA/TEA is 70 ℃, reac tion time is 6 h, the additive amount of copolymer and thiourea is 6 mg/L, 5 mg/L seperately, inhibition rate is 85.83%, the copolymer inhibitor for mild steel coupon has better inhibitive effect. Polymeric corrosion inhibitors formed a compact protective film on the surface of the carbon steel coupon, the coupon was protected from the acidic medium.
Keywords:Synthetise  Corrosion inhibitor  Steel
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