Probing the bimetallic RhCo3 cluster preserved on SiO2 after thermal treatment under O2 by hydroformylation |
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| Authors: | Lin Huang Yide Xu |
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| Affiliation: | (1) State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, PO Box 110, 116023 Dalian, People's Republic of China |
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| Abstract: | RhCo3(CO)12/SiO2, after decarbonylation under atmospheric O2 at 623 K, exhibits excellent catalytic performances in atmospheric ethylene hydroformylation at 423 K, which is consistent with the corresponding catalysis by the bimetallic cluster catalyst RhCo3/SiO2. |
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| Keywords: | silica-supported RhCo3(CO)12 oxygen treatment hydroformylation |
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