| 六硝基六氮杂异伍兹烷的研究进展(2)——N,N-二取代苄胺的脱苄反应 |
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| 引用本文： | 贾会平,欧育湘,陈博仁,徐永江,陈江涛.六硝基六氮杂异伍兹烷的研究进展(2)——N,N-二取代苄胺的脱苄反应[J].含能材料,1998,6(4):145-156. |
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| 作者姓名： | 贾会平 欧育湘 陈博仁 徐永江 陈江涛 |
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| 作者单位： | 北京理工大学化工与材料学院 |
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| 摘 要： | 讨论了Ｎ，Ｎ－二取代苄胺脱苄反应的各种方法，这些方法包括：催化氢解，催化氢转移氢解，催化氧化，亚硝解，氯甲酸酯（包括偶氮二羧酸酯）甲酰化，酸酐催化酰化，光化学反应等，分析了这些方法的特点，阐述了反应机理，并给出了典型的反应实例。
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| 关 键 词： | HNIW 二取代苄胺 脱苄反应 |
| 收稿时间： | 1998/2/10 0:00:00 |
RESEARCH PROGRESS OF HEXANITROHEXAAZAISOWURTZITANE(2) DEBENZYLATION OF N,N-DISUBSTITUTED BENZYLAMINES |
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| Jia Hui-ping,Ou Yu-xiang,Chen Bo-ren,Xu Yong-jiang and Chen Jiang-tao.RESEARCH PROGRESS OF HEXANITROHEXAAZAISOWURTZITANE(2) DEBENZYLATION OF N,N-DISUBSTITUTED BENZYLAMINES[J].Chinese Journal of Energetic Materials,1998,6(4):145-156. |
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| Authors: | Jia Hui-ping Ou Yu-xiang Chen Bo-ren Xu Yong-jiang and Chen Jiang-tao |
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| Affiliation: | College of Chemical Engineering and Material Sciences,Beijing Institute of Technology,Beijing 100081;College of Chemical Engineering and Material Sciences,Beijing Institute of Technology,Beijing 100081;College of Chemical Engineering and Material Sciences,Beijing Institute of Technology,Beijing 100081;College of Chemical Engineering and Material Sciences,Beijing Institute of Technology,Beijing 100081;College of Chemical Engineering and Material Sciences,Beijing Institute of Technology,Beijing 100081 |
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| Abstract: | The debenzylation methods of N,N disubstituted benzylamines are reviewed. Based on analyzing,the characteristics of these methods,the debenzylation mechanism and process are discussed with the typical reaction examples. The debenzylation methods consist of catalytic hydrogenolysis,catalytic transfer hydrogenolysis,catalytic oxidation,nitrosolysis,formylation by chloroformate (including azodicarboxylic acid esters),catalytic carbonylation by acid anhydride and photochemical reactions et al. |
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| Keywords: | debenzylation hexanitrohexaazaisowurtzitane(HNIW) N N disubstituted benzylamine |
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