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混凝土在海洋环境和除冰盐条件下的氯离子扩散行为
引用本文:陈浩宇,余红发,刘连新,翁智财,蒋宏伟,李美丹.混凝土在海洋环境和除冰盐条件下的氯离子扩散行为[J].华中科技大学学报(城市科学版),2005,22(3):48-52.
作者姓名:陈浩宇  余红发  刘连新  翁智财  蒋宏伟  李美丹
作者单位:1. 沈阳建筑大学,材料科学与工程学院,辽宁,沈阳,110168
2. 南京航空航天大学,土木工程系,江苏,南京,210016
3. 青海大学,土木工程系,青海,西宁,810016
基金项目:国家863计划资助项目(2002AA335020);国家自然科学基金资助项目(50178044);国家863计划西部新材料行动资助项目(2003AA33X100).
摘    要:采用化学分析方法测定了普通混凝土(OPC)和高性能混凝土(HPC)在3种除冰盐条件和3种海洋区域暴露100d后的自由氯离子浓度分布.结果表明:氯盐暴露环境对混凝土的氯离子扩散行为具有显著的影响.在相同扩散深度时,混凝土内部自由氯离子浓度的大小顺序是除冰盐环境〉海洋环境.OPC〉HPC.混凝土表观氯离子扩散系数的规律是OPC〉HPC.进一步的研究指出.除冰盐环境比海洋环境更恶劣.HPC比OPC更适应恶劣的氯盐环境。

关 键 词:普通混凝土(OPC)  高性能混凝土(HPC)  除冰盐  氯离子扩散  表观扩散系数
文章编号:1672-7037(2005)03-0048-05
收稿时间:2004-12-22
修稿时间:2004年12月22

Chloride Diffusion of Concretes Exposed to Marine Environment and Deicing Salt
CHEN Hao-yu,YU Hong-fa,LIU Lian-xin,WENG Zhi-cai,JIANG Hong-wei,LI Mei-dan.Chloride Diffusion of Concretes Exposed to Marine Environment and Deicing Salt[J].Journal of Huazhong University of Science and Technology,2005,22(3):48-52.
Authors:CHEN Hao-yu  YU Hong-fa  LIU Lian-xin  WENG Zhi-cai  JIANG Hong-wei  LI Mei-dan
Abstract:Concentration profiles of free chlorides in ordinary portland cement c oncrete (OPC) and high performance concrete (HPC), which have been exposed to 3 diffe rent deicing salt and 3 varied ocean environments for 100 days, are determined b y using chemical analysis method. Results show that chlorides diffusion in con crete dependes remarkably on the exposing environments. Concentration of fre e chlorides in concretes exposed to deicing salts is larger than that in the sam e depth of concretes that exposed to ocean environments. When compared with the same conditions, concentration of free chlorides in OPC is larger than that in H PC. The apparent chloride diffusion coefficient of OPC is lager than that of HPC . Further researches show that deicing salts are severer to concretes than ocean environments, and HPC is more applicable to chloride attacking environments tha n OPC.
Keywords:ordinary portland cement concrete (OPC)  high performance concrete (HPC)  deicing salt  chloride ion diffusion  apparent diff usion coefficient
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