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Joining of Cf/SiBCN composite with CuPd-V filler alloy
Authors:Wen-Wen Li  Bo Chen  La-Mei Cao  Wei Liu  Hua-Ping Xiong  Yao-Yong Cheng
Affiliation:1. Welding and Plastic Forming Division, Beijing Institute of Aeronautical Materials, Beijing 100095, China;2. Science and Technology on Advanced High Temperature Structural Materials Laboratory, Beijing Institute of Aeronautical Materials, Beijing 100095, China
Abstract:Two compositions of CuPd-V system filler alloy were designed for joining the Cf/SiBCN composite. Their dynamic wettability on the Cf/SiBCN composite was studied with the sessile drop method. The CuPd-8V alloy exhibited a contact angle of 57° after holding at 1170?°C for 30?min, whereas for CuPd-13V alloy, a lower contact angle of 28° can be achieved after heating at 1200?°C for 20?min. Sound Cf/SiBCN joints were successfully produced using the latter filler alloy under the brazing condition of (1170-1230)°C for 10?min. The results showed that the active element V strongly diffused to the surface of Cf/SiBCN composite, with the formation of V2C/VN reaction layer. The microstructure in the central part of the joint brazed at 1200?°C was characterized by the V2C/VN particles distributing scatteringly in CuPd matrix. The corresponding joints showed the maximum three-point bend strength of 82.4?MPa at room temperature. When the testing temperature was increased to 600?°C, the joint strength was even elevated to 108.8?MPa. Furthermore, the joints exhibited the strength of 92.4?MPa and 39.8?MPa at 800?°C and 900?°C, respectively.
Keywords:Wettability  Joint strength  Interfacial reaction
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