Towards suppressing dielectric loss of GO/PVDF nanocomposites with TA-Fe coordination complexes as an interface layer |
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Authors: | Ying Gong Wenying Zhou Zijun Wang Li Xu Yujia Kou Huiwu Cai Xiangrong Liu Qingguo Chen Zhi-Min Dang |
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Affiliation: | 1. College of Chemistry and Chemical Engineering, Xi’an University of Science & Technology, Xi’an 710054, China;2. Key Laboratory of Engineering Dielectrics and Its Application, Ministry of Education, Harbin University of Science and Technology, Harbin 150080, China;3. Shanghai Research Institute of Petrochemical Technology, Shanghai 201208, China;4. State Key Laboratory of Power System and Department of Electrical Engineering, Tsinghua University, Beijing 100084, China |
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Abstract: | In this work, graphene oxide (GO) nanosheets with surface modification by Tannic and Fe coordination complexes (TA-Fe) were incorporated into poly(vinylidene fluoride) (PVDF) to prepare high constant but low loss polymer nanocomposites, and the effect of TA-Fe interlayer on dielectric properties of the GO@TA-Fe/PVDF nanocomposites was investigated. The results indicate that the dosage, mixing ratio, and reaction time of TA-Fe complexes have obvious influences on the dielectric properties of the nanocomposites. Furthermore, the TA-Fe interlayer significantly influences the electrical properties of GO@TA-Fe nanoparticles and their PVDF composites, and the GO@TA-Fe/PVDF composites exhibit superior dielectric properties compared with raw GO/PVDF. Dielectric losses of the GO@TA-Fe/PVDF are significantly suppressed to a rather low level owing to the presence of TA-Fe layer, which serves as an interlayer between the GO sheets, thus preventing them from direct contacting with each other. Additionally, the dynamic dielectric relaxation of the GO/PVDF and GO@TA-Fe/PVDF nanocomposites was investigated in terms of temperature. |
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Keywords: | Dielectric properties Polymer nanocomposites Interface layer Relaxation |
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