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Microscopic Properties of Long-Period Ordering in Al-Rich TiAl Alloys
Authors:S Hata  T Nakano  N Kuwano  M Itakura  S Matsumura  Y Umakoshi
Affiliation:(1) Department of Engineering Sciences for Electronics and Materials, Kyushu University, Kasuga 816-8580, Japan;(2) Course of Materials Science & Engineering, Division of Materials & Manufacturing Science, Osaka University, Suita 565-0871, Japan;(3) Art, Science and Technology Center for Cooperative Research, Kyushu University, Kasuga 816-8580, Japan;(4) Department of Applied Quantum Physics and Nuclear Engineering, Kyushu University, Fukuoka 819-0395, Japan
Abstract:The ordering mechanism of long-period superstructures (LPSs) in Al-rich TiAl alloys has been investigated by high-resolution transmission electron microscopy (HRTEM). The LPSs are classified in terms of arrangements of base clusters with different shapes and compositions formed in Ti-rich (002) layers of L10-TiAl matrix: square Ti4Al, fat rhombus Ti3Al, and lean rhombus Ti2Al type clusters. The HRTEM observations revealed that antiphase boundaries of long-range-ordered LPS domains and short-range-ordered microdomains are constructed by various space-filling arrangements of the base clusters. Such a microscopic property characterized by the base clusters and their arrangements is markedly analogous to that of the $$ {\left\langle {{\text{1,1/2,0}}} \right\rangle } $$* special-point ordering alloys such as Ni-Mo. This article is based on a presentation given in the symposium entitled “Materials Behavior: Far from Equilibrium” as part of the Golden Jubilee Celebration of Bhabha Atomic Research Centre, which occurred December 15–16, 2006 in Mumbai, India.
Contact Information S. Hata (Associate Professor)Email:
Keywords:
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