| Abstract: | Amphiphilic ABA triblock copolymers of poly(ethylene oxide) (PEO) with methyl methacrylate (MMA) were prepared by atom transfer radical polymerization in bulk and in various solvents with a difunctional PEO macroinitiator and a Cu(I)X/N,N,N′,N″,N″‐pentamethyldiethylenetriamine catalyst system at 85°C where X=Cl or Br. The polymerization proceeded via controlled/living process, and the molecular weights of the obtained block copolymers increased linearly with monomer conversion. In the process, the polydispersity decreased and finally reached a value of less than 1.3. The polymerization followed first‐order kinetics with respect to monomer concentration, and increases in the ethylene oxide repeating units or chain length in the macroinitiator decreased the rate of polymerization. The rate of polymerization of MMA with the PEO chloro macroinitiator and CuCl proceeded at approximately half the rate of bromo analogs. A faster rate of polymerization and controlled molecular weights with lower polydispersities were observed in bulk polymerization compared with polar and nonpolar solvent systems. In the bulk polymerization, the number‐average molecular weight by gel permeation chromatography (Mn,GPC) values were very close to the theoretical line, whereas lower than the theoretical line were observed in solution polymerizations. The macroinitiator and their block copolymers were characterized by Fourier transform infrared spectroscopy, 1H‐NMR, matrix‐assisted laser desorption ionization time‐of‐flight mass spectrometry, thermogravimetry (TG)/differential thermal analysis (DTA), differential scanning calorimetry (DSC), and scanning electron microscopy (SEM). TG/DTA studies of the homo and block copolymers showed two‐step and multistep decomposition patterns. The DSC thermograms exhibited two glass‐transition temperatures at ?17.7 and 92°C for the PEO and poly(methyl methacrylate) (PMMA) blocks, respectively, which indicated that microphase separation between the PEO and PMMA domains. SEM studies indicated a fine dispersion of PEO in the PMMA matrix. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 97: 989–1000, 2005 |
