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Synthesis and characteristics of semi‐interpenetrating polymer network hydrogels based on chitosan and poly(hydroxy ethyl methacrylate)
Authors:Seon Jeong Kim  Su Ryon Shin  Dong Ik Shin  In Young Kim  Sun I Kim
Abstract:Semi‐interpenetrating polymer networks (semi‐IPNs), composed of chitosan and poly(hydroxy ethyl methacrylate) hydrogels, were prepared and the effects of various pH, temperatures, and an electric‐field on the swollen hydrogels were investigated. The swelling kinetics increased rapidly, reaching equilibrium within 60 min. Semi‐IPN hydrogels exhibited relatively high swelling ratios, 150~350%. The swelling ratio increased when the pH of the buffer was below pH 7 as a result of the dissociation of ionic bonds. Semi‐IPN hydrogels showed electroresponsiveness by shrinking when an electric field was applied. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 96: 86–92, 2005
Keywords:chitosan  poly(hydroxyethyl methacrylate)  swelling behavior  pH sensitive
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