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嵌段聚合物模板合成CdSe纳米粒子及表征
引用本文:陈延明,左孝为,李三喜. 嵌段聚合物模板合成CdSe纳米粒子及表征[J]. 高分子材料科学与工程, 2011, 0(2): 23-25,29
作者姓名:陈延明  左孝为  李三喜
作者单位:沈阳工业大学石油化工学院;
基金项目:辽宁省科技厅博士基金项目资助(200644)
摘    要:以羟基化SBS(SBS-OH)为模板,N,N-二甲基甲酰胺(DMF)为溶剂,硒代硫酸钠及乙酸镉为前驱物,"原位反应"制备了CdSe纳米粒子.通过紫外-可见吸收光谱、荧光光谱(PL)和透射电子显微镜(TEM)等方法对CdSe纳米粒子的光学性质及形貌进行了表征.结果表明,利用SBS-0H的两亲性质,可以在DMF中得到具有明...

关 键 词:苯乙烯-丁二烯-苯乙烯嵌段共聚物  嵌段聚合物  硒化镉  纳米粒子

Synthesis and Characterization of CdSe Nanoparticles Templated by Block Copolymer
Yanming Chen,Xiaowei Zuo,Sanxi Li. Synthesis and Characterization of CdSe Nanoparticles Templated by Block Copolymer[J]. Polymer Materials Science & Engineering, 2011, 0(2): 23-25,29
Authors:Yanming Chen  Xiaowei Zuo  Sanxi Li
Affiliation:Yanming Chen,Xiaowei Zuo,Sanxi Li(School of Petrochemical Engineering,Shenyang University of Technology,Liaoyang 111003,China)
Abstract:CdSe nanoparticles were synthesized by using hydroxylated poly(styrene-b-butadiene-b-styrene)(SBS-OH) as template,N,N-dimethylformamide(DMF) as solvent,cadmium acetate and Na2SeSO3 as precursors.The optical properties and morphologies for the synthesized CdSe nanoparticles were determined by UV-Vis absorption spectroscopy,photoluminescence spectroscopy(PL) and electron transmission microscopy(TEM) measurements.The results show that CdSe nanoparticles with apparent quantum confinement effect can be obtained ...
Keywords:poly(styrene-b-butadiene-b-styrene)  block copolymers  cadmium selenide  nanoparticles  
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