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分子量对聚丙烯拉伸微孔膜结构的影响
引用本文:刘葭,丁治天,刘正英,杨伟,冯建民,杨鸣波. 分子量对聚丙烯拉伸微孔膜结构的影响[J]. 高分子材料科学与工程, 2011, 0(2): 64-67
作者姓名:刘葭  丁治天  刘正英  杨伟  冯建民  杨鸣波
作者单位:四川大学高分子科学与工程学院高分子材料工程国家重点实验室;
基金项目:国家重点基础研究项目(2005CB623808)资助
摘    要:
以重均分子量和分子量分布不同的三种聚丙烯树脂为原料,采用熔融挤出-退火-室温拉伸-热拉伸的方法制备了聚丙烯微孔膜.采用凝胶渗透色谱(GPC)、松弛时间谱、差示扫描量热(DSC)、扫描电镜(SEM)等测试手段表征了分子量对最终微孔膜结构的影响.结果表明,重均分子量为587.0 kg/mol、特征松弛时间最长的T30S粒料...

关 键 词:聚丙烯  拉伸法  微孔膜  重均分子量  片晶结构

Effect of Molecular Weight on Stretched Polypropylene Microporous Membranes
Jia Liu,Zhitian Ding,Zhengying Liu,Wei Yang,Jianmin Feng,Mingbo Yang. Effect of Molecular Weight on Stretched Polypropylene Microporous Membranes[J]. Polymer Materials Science & Engineering, 2011, 0(2): 64-67
Authors:Jia Liu  Zhitian Ding  Zhengying Liu  Wei Yang  Jianmin Feng  Mingbo Yang
Affiliation:Jia Liu,Zhitian Ding,Zhengying Liu,Wei Yang,Jianmin Feng,Mingbo Yang(College of Polymer Science and Engineering,State Key Laboratory of Polymer Materials Engineering,Sichuan University,Chengdu 610065,China)
Abstract:
Three kinds of polypropylene with different weight-average molecular weight and molecular weight distribution were applied to form microporous membranes by melt-extrusion,annealing,cold stretching and hot stretching method in this research.The effect of molecular weight on microporous membranes was characterized by gel permeation in chromatography(GPC),relaxation spectra,differential scanning calorimetry(DSC) and scanning electron microscope(SEM).The results show that T30S particle with weight-average molec...
Keywords:polypropylene  stretching  microporous membranes  weight-average molecular weight  lamellar crystalline structure  
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