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Reductive roasting of nickel laterite ore with sodium sulfate for Fe-Ni production. Part I: Reduction/sulfidation characteristics
Authors:Mingjun Rao  Guanghui Li  Xin Zhang  Jun Luo  Zhiwei Peng
Affiliation:1. School of Minerals Processing and Bioengineering, Central South University, Changsha, Hunan, Chinaliguangh@csu.edu.cn;3. School of Minerals Processing and Bioengineering, Central South University, Changsha, Hunan, China
Abstract:The selective reduction of nickel and adequate growth of ferronickel grains are imperative for efficient preparation of ferronickel from nickeliferous laterite ore via the process of direct reduction followed by magnetic separation. In Part I, reduction/sulfidation behaviors of a saprolitic laterite ore in the presence of sodium sulfate were investigated, with an emphasis on thermodynamic analysis, selective reduction/sulfidation ratios and kinetics. To separate the interactions between Ni and Fe, chemical titration analysis was adopted to determine the contents of various Ni and Fe species in the roasted pellets, and a modified equation to assay metallic iron content was proposed.
Keywords:Ferronickel  laterite ore  selective reduction  sulfidation  sodium sulfate
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