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Enhancing the ozonation of industrial wastewater with electrochemically generated copper(II) ions
Authors:Carlos Carbajal  Carlos Barrera-Díaz  G. Roa-Morales  P. Balderas-Hersnández  R. Natividad  Bryan Bilyeu
Affiliation:1. Centro Conjunto de Investigación en Química Sustentable, UAEM-UNAM, Carretera Toluca-Atlacomulco, Toluca Estado de México, Méxicocebarrerad@uaemex.mx;3. Centro Conjunto de Investigación en Química Sustentable, UAEM-UNAM, Carretera Toluca-Atlacomulco, Toluca Estado de México, México;4. Department of Chemistry, Xavier University of Louisiana, New Orleans, Louisiana, USA
Abstract:This study evaluates the effect of adding electrochemical copper(II) ions into an ozonation process for treating industrial wastewater. Combining the processes resulted in a synergy that enhanced the reduction of physicochemical parameters (COD, TOC, color, turbidity, Z-Potential, and conductivity). In only 15 minutes the integrated process reduced the COD by 83%, TOC by 78 %, color by 93%, turbidity by 77%, and conductivity by 27% at relatively low current density (12.5 mA cm?2). Thus, the combination of the electrochemical and ozonation processes noticeably improves wastewater quality, decreases the process time, and reduces the sludge production.
Keywords:Oxidation  physicochemical treatment  sludge reduction  wastewater treatment
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