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Removal of heavy metals from wastewater using magnetic nanocomposites: Analysis of the experimental conditions
Authors:María F Horst  Mariana Alvarez  Verónica L Lassalle
Affiliation:1. Departamento de Química, Universidad Nacional del Sur (UNS), Bahía Blanca, Buenos Aires, Argentinamfhorst@uns.edu.ar;3. Departamento de Química, Universidad Nacional del Sur (UNS), Bahía Blanca, Buenos Aires, Argentina
Abstract:This contribution provides insight on the elimination of heavy metals from water resources using magnetic separation. Nanocomposites based on magnetite and chitosan were prepared. An exhaustive characterization of the magnetic adsorbents was developed. Adsorption assays were performed in batch using Cu, Zn, Cd, and Cr as model heavy metals. The efficiency of magnetic adsorbents followed the order: Cu > Cd > Zn > Cr, with maximum values of 188, 159, 72, and 46 mg of Me/g of nanocomposite, respectively. Kinetics and mechanistic issues were studied. The magnetic materials were efficient for five to eight cycles using Cu(II),Cd(II), and Cr(VI).
Keywords:Magnetic separation  nanoadsorbents  chitosan  heavy metals  iron oxides  nanocomposites
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