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Assessment of Oxygen Control and Its Effect on Inclusion Characteristics during Electroslag Remelting of Die Steel
Authors:Cheng‐Bin Shi  Xi‐Chun Chen  Han‐Jie Guo  Zi‐Jiang Zhu  Hao Ren
Affiliation:1. School of Metallurgical and Ecological Engineering, University of Science and Technology Beijing, Beijing 100083, P. R. China;2. State Key Laboratory of Advanced Metallurgy, University of Science and Technology Beijing, Beijing 100083, P. R. China;3. Research Institute of High Temperature Materials, Central Iron and Steel Research Institute, Beijing 100081, P. R. China
Abstract:Deoxidation during electroslag remelting of S136 die steel was experimentally studied. The characteristics of inclusions in the electrode and ESR ingots were determined by image analyzer and SEM‐EDS. The results show that the oxygen content can be reduced from 89 ppm in the electrode to the lowest (12 ppm) in the ingot only when protective Ar gas remelting in combination with specially designed slag deoxidation treatment were employed simultaneously. The proportion of the oxygen combined as oxide inclusions increases with decreasing the total oxygen content in ESR ingot. The original inclusions in the electrode are mainly large (Mn,Cr)S and the large inclusions in the form of Al2O3 core surrounded by an outer sulfide layer, besides a few pure Al2O3 inclusions. After ESR process, while only pure Al2O3 inclusions with the size of about 1 µm were observed in ESR ingots. The large inclusions in the electrode were removed during ESR process. With higher oxygen content in the ingot, the contents of inclusions and large inclusions would be relatively higher. The results from industrial experiments have confirmed the availability of the present oxygen control technique. The mechanisms of oxygen behavior and control as well as inclusion evolution during ESR process were proposed based on experimental results along with thermodynamic analysis.
Keywords:electroslag remelting  inclusions  oxygen control  sulfide  evolution mechanism  thermodynamic analysis
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