A 2D brickwall architecture from a double-T-shaped ligand and hybrid coordinatively unsaturated copper: Synthesis,structure, and framework dynamic |
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Authors: | Shengjun Deng Ning Zhang Weiming Xiao Chao Chen |
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Affiliation: | Department of Chemistry, Nanchang University, Xuefu Road, No. 999, Nanchang 330031, PR China |
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Abstract: | A double-T-shaped ligand (H4BPTC) as the spacer has been first used to direct the assembly of a 2D coordination polymer with brickwall network topology, Cu2(BPTC)(Im)4(H2O)(DMF)]n (1) (DMF = N,N-dimethylformamide, H4BPTC = Biphenyl-3,3′,4,4′-tetracarboxylic acid, Im = imidazole), which exhibits an interesting framework dynamic upon de-/resolvation. |
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