Synthesis,X-ray structure,spectroscopic properties,and theoretical investigations of dinuclear imidazole molybdenum(VI) complex with long MoO bands期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

Synthesis,X-ray structure,spectroscopic properties,and theoretical investigations of dinuclear imidazole molybdenum(VI) complex with long MoO bands

Authors:	Yan-Wen Lin Yi-Ping Tong Chi Yang Yan-Ru Lin

Affiliation:	1. Department of Biology, Hanshan Normal University, Chaozhou 521041, People’s Republic of China;2. Institute of Inorganic Chemistry, Hanshan Normal University, East Bridge Street, Chaozhou 521041, People’s Republic of China;3. Department of Chemistry, Hanshan Normal University, Chaozhou 521041, People’s Republic of China

Abstract:	One new dinuclear multioxomolybdenum(VI) complex containing long MoO bands with imidazole, Mo₂O₆(imi)₄] (1) (imi = imidazole), has been prepared and characterized, and the geometric structure, electronic structure and spectroscopic properties, investigated experimentally and theoretically. The rarely observed long MoO bonds in 1 (ca. 0.15 Å longer than documents previously) are analysed by orbital structure analysis. The electronic origins of the optical transitions are also mainly related to the MoO groups with ligand-to-metal charge transfer (LMCT) nature (P_terminal-oxo → d_Mo).

Keywords:
本文献已被 ScienceDirect 等数据库收录！