Competition between 3d metals(II) and palladium(II) in the reaction of heterobimetallic complexes Pd(μ-OOCMe)4M(OH2) (M = Ni,Co, Mn) with azobenzene期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

Competition between 3d metals(II) and palladium(II) in the reaction of heterobimetallic complexes Pd(μ-OOCMe)4M(OH2) (M = Ni,Co, Mn) with azobenzene

Authors:	Sergei E Nefedov Elena V Perova Ilya A Yakushev Natalia Yu Kozitsyna Michael N Vargaftik Ilya I Moiseev

Affiliation:	N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninsky prospect 31, 119991 Moscow, Russian Federation

Abstract:	The reaction of Pd^II(μ-OOCMe)₄M^II(OH₂) (M = Ni, Co, Mn) with azobenzene under mild conditions produces the homonuclear complex with ortho-metallated azobenzene (PhN = NC₆H₄)₂Pd₂(μ-OOCMe)₂ (4) in higher than 90 % yield as the sole Pd-containing reaction product, while the co-metals are recovered as the corresponding M^II acetates.

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