A two-dimensional copper polymer constructed from rod-shaped ferromagnetic secondary building units |
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| Authors: | Zhao-Xi Wang Ming-Xing Li Min Shao Hong-Ping Xiao |
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| Affiliation: | 1. Department of Chemistry, College of Science, Shanghai University, Shanghai 200444, PR China;2. Instrumental Analysis and Research Center, Shanghai University, Shanghai 200444, PR China;3. School of Chemistry and Materials Engineering, Wenzhou University, Wenzhou 325027, PR China |
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| Abstract: | On the basis of rod-shaped secondary building units (SBUs), a novel two-dimensional (2D) azide–copper polymer, Cu3(N3)4(anol)2]∞ (1; anol = aminoethanol), was synthesized and structurally characterized. Complex 1 is a neutral 2D coordination network consisting of trinuclear copper(II) clusters Cu3(N3)4(anol)2] connected with the bridge of end-end (EE) azide group. Magnetic data analysis shows that a metamagnetic behavior is observed for 1 which is associated with significant ferromagnetic coupling intracluster over 4 K. |
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